CATALYTIC-HYDROGENATION OF ALKYNES TO CIS-ALKENES ON A MODIFIED BORON NICKEL-CATALYST

被引：1
|
作者：
SIIMER, EK
PETROVA, SS
机构：
[1] Institute of Chemistry, Academy of Sciences of Estonia, Tallinn
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 12期
关键词：
D O I：
10.1007/BF00959736
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrogenation of alkynes from decyne and dodecyne (C-10-C-12) with the triple bond at C3, C4, C5, and C6 led to the corresponding alkenes on a boron-nickel catalyst modified by 1-phenyl-2,3-dimethyl-4-amino-5-pyrazolone (4-aminoantipyrene). The stereospecificity for formation of the cis-alkenes was 95-98%.
引用
下载
收藏
页码：2516 / 2518
页数：3
相关论文
共 50 条
12345