CATALYTIC-HYDROGENATION OF ALKYNES TO CIS-ALKENES ON A MODIFIED BORON NICKEL-CATALYST

被引：1

作者：

SIIMER, EK

PETROVA, SS

机构：

[1] Institute of Chemistry, Academy of Sciences of Estonia, Tallinn

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 12期

关键词：

D O I：

10.1007/BF00959736

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of alkynes from decyne and dodecyne (C-10-C-12) with the triple bond at C3, C4, C5, and C6 led to the corresponding alkenes on a boron-nickel catalyst modified by 1-phenyl-2,3-dimethyl-4-amino-5-pyrazolone (4-aminoantipyrene). The stereospecificity for formation of the cis-alkenes was 95-98%.

引用

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页码：2516 / 2518

页数：3

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