THE NEGATIVE-ION PHOTOELECTRON (PHOTODETACHMENT) SPECTRA OF NO-(H2O)N=1,2

被引：29

作者：

EATON, JG

ARNOLD, ST

BOWEN, KH

机构：

[1] The Department of Chemistry, The Johns Hopkins University, Baltimore

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 1990年 / 102卷

关键词：

D O I：

10.1016/0168-1176(90)80066-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

We have recorded the negative ion photoelectron spectra of NO- (H2O)n = 1.2 and NO- (D2O)1 using 2.540 eV photons. Vertical detachment energies, adiabatic electron affinities, and anion-single solvent dissociation (sequential solvation) energies were determined from these spectra. For NO- (H2O)1 and NO- (H2O)2, the ion-solvent dissociation energies for the loss of single water molecules were found to be 0.72 and 0.68 eV, respectively. This system is discussed in relation both to other hydrated-anion complexes and to other NO- complexes.

引用

页码：303 / 312

页数：10

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