Comparison of catalytic reactivities of triphenylphosphine complexes of Ru, Rh, Pd, Fe, Co, Ni in the maleic anhydride hydrogenation

被引:0
|
作者
Li, JP [1 ]
Li, ZS [1 ]
Tian, X [1 ]
Yang, KH [1 ]
机构
[1] Liaoning Normal Univ, Dept Chem, Dalian 116022, Peoples R China
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The sequence of homogeneous catalytic reactivity of triphenylphosphine complexes of Ru, Rh Pd, Fe, Co, Ni in the maleic anhydride hydrogenation is RuCl2 (PPh3)(3)>RhCl(PPh3)(3)>NiCl2 (PPh3)(2)>CoCl2(PPh3)(2)>FeCl2(PPh3)(2)>PdCl2(PPh3)(2). This is consistent with the metal atoms' ionization potentials.
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页码:343 / 344
页数:2
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