ACYCLIC DIENE METATHESIS (ADMET) OLIGOMERIZATION OF DIVINYLTETRAMETHYLDISILOXANE IN THE PRESENCE OF RHODIUM AND RUTHENIUM COMPLEXES

被引：28
|
作者：
MARCINIEC, B
LEWANDOWSKI, M
机构：
[1] Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Poznan, 60-780
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS | 1995年 / 5卷 / 02期
关键词：
ADMET POLYMERIZATION; DIVINYLTETRAMETHYLDISILOXANE; RHODIUM AND RUTHENIUM CATALYSTS;
D O I：
10.1007/BF01058140
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Acyclic diene metathesis (ADMET) polymerization of divinyltetramethyl-disiloxane in the presence of rhodium [RhCl(COD)](2) and ruthenium RuCl2(PPh3)(3) catalysts led predominantly to linear oligomers [M(n)=1815, M(w)/M(n) = 1.16] if the rhodium catalyst was used or to mixtures of dimeric and trimeric oligomers if the ruthenium complex was applied. The rhodium complex appeared to be the first effective catalyst for ADMET polymerization of divinyldisubstituted organosilicon compounds.
引用
收藏
页码：115 / 122
页数：8
相关论文
共 50 条
  • [31] Exploring solvent effects with alternating acyclic diene metathesis (ADMET) polymerization
    Schulz, Michael D.
    Wagener, Kenneth B.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [32] ACYCLIC DIENE METATHESIS (ADMET) POLYMERIZATION - SYNTHESIS OF PERFECTLY LINEAR POLYETHYLENE
    OGARA, JE
    WAGENER, KB
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1993, 14 (10): : 657 - 662
  • [33] Tactic precision polymers via acyclic diene metathesis (ADMET) chemistry
    Few, Chip
    Martinez, Henry
    Wagener, Ken B.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [34] A Photocurable, Photoluminescent, Polycarbosilane Obtained by Acyclic Diene Metathesis (ADMET) Polymerization
    Rathore, Jitendra S.
    Interrante, Leonard V.
    MACROMOLECULES, 2009, 42 (13) : 4614 - 4621
  • [35] Acyclic diene metathesis (ADMET) polymerization. The synthesis of unsaturated polyesters
    Patton, J.T.
    Boncella, J.M.
    Wagener, K.B.
    Journal of Japanese Society of Tribologists, 1992, 37 (06) : 3862 - 3867
  • [36] ACYCLIC DIENE METATHESIS (ADMET) POLYMERIZATION - SYNTHESIS OF PERFECTLY LINEAR POLYETHYLENE
    OGARA, JE
    WAGENER, KB
    HAHN, SF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 60 - POLY
  • [37] ACYCLIC DIENE METATHESIS (ADMET) DEPOLYMERIZATION OF FUNCTIONALIZED FURAN BASED POLYMERS
    VISWANATHAN, T
    GOMEZ, FJ
    WAGENER, KB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 54 - POLY
  • [38] ACYCLIC DIENE METATHESIS (ADMET) POLYMERIZATION - SYNTHESIS OF UNSATURATED POLY(CARBOSILOXANES)
    WAGENER, KB
    SMITH, DW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 53 - POLY
  • [39] Ferrocene-containing polymers synthesized by acyclic diene metathesis (ADMET) polymerization
    Zhang, Hao
    Liu, Fang
    Cao, Jing
    Ling, Li
    Sun, Ran-feng
    CHINESE JOURNAL OF POLYMER SCIENCE, 2016, 34 (02) : 242 - 252
  • [40] Acyclic Diene Metathesis (ADMET) as Powerful Tool for Functional Polymers with Versatile Architectures
    Shuang Liu
    Jing Yan
    Qiuyu Zhang
    Yi Yan
    Journal of Inorganic and Organometallic Polymers and Materials, 2022, 32 : 3368 - 3394
12345