The vibrational spectra of the layered compounds KSb(PO4)(2) and CsM(PO4)(2) (M=Sb, Ta, Nb). Normal coordinate analysis of KSb(PO4)(2)

被引：0
|
作者：
Husson, E
Repelin, Y
Piffard, Y
Verbaere, A
机构：
[1] ECOLE CENT PARIS, CHIM PHYS SOLIDE LAB, URA CNRS 453, F-92295 CHATENAY MALABRY, FRANCE
[2] IMN, CHIM SOLIDE LAB, CNRS, UMR 110, F-44072 NANTES 3, FRANCE
[3] CNRS, CRPHT, F-45071 ORLEANS 2, FRANCE
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1995年 / 32卷 / 11期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Infrared and Raman spectra on powder samples of KSb(PO4)(2), CsSb(PO4)(2), CsTa(PO4)(2) and CsNb(PO4)(2) and polarized Raman spectra on a single crystal of KSb(PO4)(2) were recorded. A normal coordinate analysis using a generalized force field was performed for KSb(PO4)(2). The whole results allowed an assignment of the observed frequencies. It was possible to characterize the P-O, Sb-O and M-O bonds (M = alkaline cation) in layered phosphatoantimonates. The strength of the Sb-O, Ta-O and Nb-O bonds is compared.
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页码：1077 / 1088
页数：12
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