RbCuFe(PO4)(2)

被引：8
|
作者：
Badri, Abdessalem [1 ]
Hidouri, Mourad [1 ]
Ben Amara, Mongi [1 ]
机构：
[1] Univ Monastir, Fac Sci, Monastir 5019, Tunisia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
data-to-parameter ratio = 26.6; meanω(P - O) = 0.006 A °; Rfactor = 0.046; single-crystal X-ray study; T = 293 K; wRfactor = 0.126;
D O I：
10.1107/S1600536813019569
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new iron phosphate, rubidium copper(II) iron(III) bis(phosphate), RbCuFe(PO4)(2), has been synthesized as single crystals by the flux method. This compound is isostructural with KCuFe(PO4)(2) [Badri et al. (2011), J. Solid State Chem. 184, 937-944]. Its structure is built up from Cu2O8 units of edge-sharing CuO5 polyhedra, interconnected by FeO6 octahedra through common corners to form undulating chains that extend infinitely along the [011] and [011] directions. The linkage of such chains is ensured by the PO4 tetraedra and the resulting three-dimensional framework forms quasi-elliptic tunnels parallel to the [101] direction in which the Rb+ cations are located.
引用
收藏
页码：I52 / +
页数：7
相关论文
共 50 条
  • [1] CRYSTAL-STRUCTURES OF CSTA(PO4)2 AND TAH(PO4)2
    NIKOLAEV, VP
    SADIKOV, GG
    LAVROV, AV
    PORAIKOSHITS, MA
    [J]. INORGANIC MATERIALS, 1983, 19 (06) : 876 - 880
  • [2] Structural and thermal studies of SrU(PO4)2 and BaU(PO4)2
    Keskar, Meera
    Vats, B. G.
    Phatak, R.
    Krishnan, K.
    Sali, S. K.
    Kannan, S.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 725 : 1199 - 1209
  • [3] HYDROTHERMAL SYNTHESIS OF MTI2(PO4)3 LITI2(PO4)3, NATI2(PO4)3, KTI2(PO4)3
    YUE, Y
    PANG, WQ
    [J]. MATERIALS RESEARCH BULLETIN, 1990, 25 (07) : 841 - 844
  • [4] SrZn(VO)(PO4)(2) and BaCd(VO)(PO4)(2): Vanadylphosphates related but not isotypic to the BaZn(VO)(PO4)(2) type
    Meyer, S
    Mertens, B
    MullerBuschbaum, H
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (08): : 985 - 988
  • [5] SrZn(VO)(PO4)2 and BaCd(VO)(PO4)2: Vanadylphosphates Related but not Isotypic to the BaZn(VO)(PO4)2 Type
    Meyer, S.
    Mertens, B.
    Mueller-Buschbaum, H.
    [J]. Zeitschrift fuer Naturforschung. B, Journal of Chemical Sciences, 52 (08):
  • [6] TERNARY PHOSPHATES IN THE SYSTEMS CA3(PO4)2-NA3ND(PO4)2, CA3(PO4)2-NA3U(PO4)2, CA3(PO4)2-NA3ER(PO4)2
    LAZORYAK, BI
    IVANOV, LN
    STRUNENKOVA, TV
    GOLUBEV, VN
    VITING, BN
    [J]. INORGANIC MATERIALS, 1990, 26 (02) : 283 - 286
  • [7] Crystal structures of Th(OH)PO4, U(OH)PO4 and Th2O(PO4)2.: Condensation mechanism of MIV(OH)PO4 (M = Th, U) into M2O(PO4)2
    Dacheux, Nicolas
    Clavier, Nicolas
    Wallez, Gilles
    Quarton, Michel
    [J]. SOLID STATE SCIENCES, 2007, 9 (07) : 619 - 627
  • [8] Preparation and characterization of new borophosphates of PrB(PO4)2 and TbB(PO4)2
    Morkan, Ayse
    Morkan, Izzet
    Kahveci, Gulden
    Gul, Esra
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [9] A NOVEL FORM OF CD(VO)2(PO4)2 ISOTYPIC WITH CA(VO)2(PO4)2
    LECLAIRE, A
    CHARDON, J
    GRANDIN, A
    BOREL, MM
    RAVEAU, B
    [J]. EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1993, 30 (04): : 461 - 469
  • [10] CRYSTAL STRUCTURE OF CDZN2(PO4)2 AND CD2ZN(PO4)2
    CALVO, C
    STEPHENS, JS
    [J]. CANADIAN JOURNAL OF CHEMISTRY, 1968, 46 (06): : 903 - &
12345