URATE COMPLEXES OF DIPOSITIVE FIRST ROW TRANSITION-METAL IONS

被引：3
|
作者：
MIKULSKI, CM
HOLMAN, ME
TENER, G
DOBSON, T
EANG, S
WELSH, W
NUJOMA, Y
KARAYANNIS, NM
机构：
[1] AMOCO CHEM CO,NAPERVILLE,IL 60566
[2] BEAVER COLL,DEPT CHEM & PHYS,GLENSIDE,PA 19038
来源：
TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 05期
关键词：
D O I：
10.1007/BF00136357
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The following complexes were prepared by reacting uric acid (uaH(2)) with 3d metal(II) perchlorates in non-aqueous media: trans-[Mn(uaH)(2)(OH2)(4)], octahedral, and [Co-(uaH)(2)(OH2)(2)], tetrahedral, both involving O(8)-bound hydrogenurate; [Cu(ua)(OH2)(3)], tetrahedral, with the urate dianion binding via a ring nitrogen; and [Ni-2(uaH)(2)-(uaH(2))(ClO4)(2)(H2O)(3)], formulated as a pentacoordinated linear polymetric species, involving bidentate bridging hydrogenurate, binding through O(8) and a ring nitrogen.
引用
收藏
页码：491 / 493
页数：3
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