CAROTANOIDS AND AN ACORANOID FROM ROSA-RUGOSA LEAVES

被引：23
|
作者：
HASHIDOKO, Y
TAHARA, S
MIZUTANI, J
机构：
[1] Department of Agricultural Chemistry, Faculty of Agriculture, Hokkaido University, Kita-ku, Sapporo
来源：
PHYTOCHEMISTRY | 1991年 / 30卷 / 11期
关键词：
ROSA-RUGOSA; ROSACEAE; LEAVES; SESQUITERPENES; CAROTANOID; DAUCANOID; ACORANOID;
D O I：
10.1016/0031-9422(91)80099-M
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
In the investigation of minor sesquiterpenoids in Rosa rugosa leaves, 11 novel sesquiterpenes, eight carotane aldehydes, two carotane acids and an acoranoid, were isolated and their structures elucidated by means of chemical and spectroscopic methods. The present study showed that R. rugosa is a major source of C-14-oxygenated carotanoids. Factors associated with stereoselective oxygen-introduction in epoxidation and/or peroxidation of the carotane skeleton is also discussed.
引用
收藏
页码：3729 / 3739
页数：11
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