ANODIC-OXIDATION OF BENZYL ALCOHOL TO BENZALDEHYDE USING HYDROQUINONE AS MEDIATOR IN NONSOLVENT SYSTEM

被引：3
|
作者：
CHEN, LM
CHEN, YL
CHOU, TC
机构：
来源：
DENKI KAGAKU | 1994年 / 62卷 / 12期
关键词：
HYDROQUINONE; BENZYL ALCOHOL; BENZALDEHYDE; NONSOLVENT SYSTEM;
D O I：
10.5796/electrochemistry.62.1173
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In this study, an electrochemical synthesis system in non-solvent system was systematically studied including cyclic voltammograms, IE curves, current efficiency and yield. Hydroquinone is a practical redox mediator in this system. The yield of benzaldehyde at a fixed potential is twice of that without hydroquinone as the mediator in the non-solvent system. Effect of solvent has also been examined to compare with the non-solvent system. The addition of acetonitrile as solvent can increase the yield but reduce the current efficiency.
引用
收藏
页码：1173 / 1178
页数：6
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