MATRIX-ISOLATION STUDY OF THE INTERACTION OF EXCITED NEON ATOMS WITH BF3 - INFRARED-SPECTRA OF BF2+, BF3+ AND BF3-

被引：32

作者：

JACOX, ME

THOMPSON, WE

机构：

[1] Molecular Physics Division, National Institute of Standards and Technology, Gaithersburg

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 102卷 / 12期

关键词：

D O I：

10.1063/1.469523

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

When a Ne:BF3 sample is codeposited at approximately 5 K with a beam of neon atoms that have been excited in a microwave discharge, the infrared spectrum of the resulting solid deposit shows prominent absorptions of BF 2. All three vibrational fundamentals and the v1+v 3 combination band of BF2 isolated in solid neon are identified, and a normal coordinate analysis is conducted. In addition, infrared absorptions of the BF3+, BF2+, and BF3- molecular ions are assigned, and the processes which occur when the solid deposit is exposed to visible and ultraviolet radiation are considered.

引用

页码：4747 / 4756

页数：10

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