ELECTRON-AFFINITY OF CO(CO)(2)NO MEASURED BY NEGATIVE-ION PHOTOELECTRON-SPECTROSCOPY

被引：5
|
作者：
TURNER, NJ [1 ]
MARTEL, AA [1 ]
WALLER, IM [1 ]
机构：
[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 02期
关键词：
D O I：
10.1021/j100053a021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this work, we present the fixed-frequency (at 355 nm) negative-ion photoelectron spectrum of Co(CO)(2)NO-. Analysis of the spectrum yields the electron affinity of Co(CO)(2)NO; EA[Co(CO)(2)NO] = 1.73 +/- 0.03 eV. The lack of extensive vibrational progressions in the spectrum is consistent with the neutral species and the negative-ion having similar equilibrium geometries.
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页码：474 / 477
页数：4
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