STRUCTURE OF DI-2-PYRIDYL KETONE-HYDRATE PLATINUM(II) CHLORIDE TETRAHYDRATE

被引：20
|
作者：
SOMMERER, SO [1 ]
ABBOUD, KA [1 ]
机构：
[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270192012496
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An X-ray structural analysis of bis(di-2-pyridylmethanediol)platinum(II) dichloride tetrahydrate revealed a Pt(II) cation coordinated by four N-atom donors with two additional long-range O-atom interactions resulting in pseudo-octahedral geometry. The formation of a six-membered chelate in boat-like conformation together with the long-range off-axial interactions between Pt and O in the apical positions of the complex appear to contribute to the stability of the hydrated species.
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收藏
页码：1152 / 1154
页数：3
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