STRUCTURE OF DI-2-PYRIDYL KETONE-HYDRATE PLATINUM(II) CHLORIDE TETRAHYDRATE

被引：20
|
作者：
SOMMERER, SO [1 ]
ABBOUD, KA [1 ]
机构：
[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270192012496
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An X-ray structural analysis of bis(di-2-pyridylmethanediol)platinum(II) dichloride tetrahydrate revealed a Pt(II) cation coordinated by four N-atom donors with two additional long-range O-atom interactions resulting in pseudo-octahedral geometry. The formation of a six-membered chelate in boat-like conformation together with the long-range off-axial interactions between Pt and O in the apical positions of the complex appear to contribute to the stability of the hydrated species.
引用
收藏
页码：1152 / 1154
页数：3
相关论文
共 50 条
  • [1] Crystal structure of a copper stabilized hydrate of di-2-pyridyl ketone
    Parker, OJ
    Aubol, SL
    Breneman, GL
    [J]. POLYHEDRON, 2000, 19 (06) : 623 - 626
  • [2] Di-2-pyridyl ketone p-aminobenzoylhydrazone hydrate
    Bakir, M
    Green, O
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2002, 58 : o263 - o265
  • [3] NI(II) COMPLEXES OF DI-2-PYRIDYL KETONE
    ORTEGO, JD
    PERRY, DL
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1973, 35 (08): : 3031 - 3034
  • [4] COBALT(II) COMPLEXES OF DI-2-PYRIDYL KETONE
    ORTEGO, JD
    WATERS, DD
    STEELE, CS
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (04): : 751 - 756
  • [5] URANYL COMPLEXES WITH DI-2-PYRIDYL KETONE AND DI-2-PYRIDYL SULFIDE
    PAPPALARDO, GC
    SEMINARA, A
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1976, 38 (11): : 1993 - 1995
  • [6] Di-2-pyridyl ketone azine
    Chen, XD
    Zhang, LP
    Du, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O284 - O285
  • [7] DI-2-PYRIDYL KETONE AND BENZOTRIAZOLE COMPLEXES OF ZINC(II)
    PRADHAN, B
    RAO, DVR
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1980, 19 (01): : 72 - 74
  • [8] AN IMPROVED SYNTHESIS OF DI-2-PYRIDYL KETONE
    BLACK, DSC
    RICHNER, HL
    SRIVASTA.RC
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (09) : 1911 - &
  • [9] Chlorobis(N,N′-di-2-pyridyl ketone oximato)gold(III) hydrate
    Barry Univ, Miami Shores, United States
    [J]. Acta Crystallogr Sect C Cryst Struct Commun, pt 11 (1551-1553):
  • [10] ZINC(II), CADMIUM(II) AND MERCURY(II) COMPLEXES OF DI-2-PYRIDYL KETONE
    ORTEGO, JD
    UPALAWANNA, S
    AMANOLLAHI, S
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1979, 41 (04): : 593 - 595
12345