SYNTHESIS AND STRUCTURE OF NB3SITE6, A NEW LAYERED TERNARY NIOBIUM TELLURIDE COMPOUND

被引：38
|
作者：
LI, J
BADDING, ME
DISALVO, FJ
机构：
[1] CORNELL UNIV,DEPT CHEM,BAKER LAB,ITHACA,NY 14853
[2] RUTGERS STATE UNIV,CAMDEN COLL ARTS & SCI,DEPT CHEM,CAMDEN,NJ 08102
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 184卷 / 02期
关键词：
D O I：
10.1016/0925-8388(92)90499-Y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Nb3SiTe6, a new type of layered ternary telluride compound, has been synthesized. The structure is determined by single-crystal X-ray diffraction methods. The compound crystallizes in space group Pnma (No. 62) with Z = 4, a = 6.353(2) angstrom, b = 13.938(5) angstrom, c = 11.507(4) angstrom, V = 1018.9(6) angstrom3, R = 4.77% and R(w) = 4.88%. The structure contains sheets of mixed niobium and silicon with tellurium atoms capping both sides. The layered framework has an unusual coordination environment.
引用
收藏
页码：257 / 263
页数：7
相关论文
共 50 条
  • [41] Synthesis, crystal structure and thermoelectric properties of a new metal telluride Ba3Ag3InTe6
    Lee, M. -Y.
    Bilc, D. I.
    Symeou, E.
    Lin, Y. -C.
    Liang, I. -C.
    Kyratsi, T.
    Hsu, K. -F.
    INORGANIC CHEMISTRY FRONTIERS, 2017, 4 (09): : 1458 - 1464
  • [42] SYNTHESIS AND SOME PROPERTIES OF FEOOCH3 - NEW LAYERED COMPOUND
    KIKKAWA, S
    KANAMARU, F
    KOIZUMI, M
    INORGANIC CHEMISTRY, 1976, 15 (09) : 2195 - 2197
  • [43] NEW FAMILY OF TERNARY NIOBIUM OXIDES, A3M8021 WITH CAGE STRUCTURE
    GROULT, D
    CHAILLEUX, JM
    CHOISNET, J
    RAVEAU, B
    JOURNAL OF SOLID STATE CHEMISTRY, 1976, 19 (03) : 235 - 244
  • [44] STRUCTURE OF A NEW QUATERNARY NIOBIUM CHLORIDE WITH NB-6 CLUSTERS - CSLUNB6CL18
    IHMAINE, S
    PERRIN, C
    SERGENT, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 705 - 707
  • [45] Crystal structure of the new ternary compound Ce3RU2In3
    Kurenbaeva, Zh. M.
    Tursina, A. I.
    Murashova, E. V.
    Nesterenko, S. N.
    Gribanov, A. V.
    Seropegin, Yu. D.
    Noeel, H.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 442 (1-2) : 86 - 88
  • [46] Experimental synthesis and crystal structure refinement of a new ternary intermetallic compound Al3GaCu9
    Liang, Liuqing
    Li, Weijun
    Lu, Meiwen
    Li, Sheng
    Li, Degui
    Gu, Bin
    POWDER DIFFRACTION, 2023, 38 (03) : 215 - 219
  • [47] Synthesis and crystal structure of α and β-Rb6U5V2O23, a new layered compound
    Obbade, S
    Dion, C
    Duvieubourg, L
    Saadi, M
    Abraham, F
    JOURNAL OF SOLID STATE CHEMISTRY, 2003, 173 (01) : 1 - 12
  • [48] STRUCTURE OF BARIUM NIOBIUM SILICON OXIDE BA3NB6SI4026
    SHANNON, J
    KATZ, L
    ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1969, A 25 : S112 - &
  • [49] SYNTHESIS AND PHYSICAL-PROPERTIES OF THE NEW LAYERED TERNARY TELLURIDES MIRTE4 (M = NB, TA), AND THE STRUCTURE OF NBIRTE4
    MAR, A
    IBERS, JA
    JOURNAL OF SOLID STATE CHEMISTRY, 1992, 97 (02) : 366 - 376
  • [50] STRUCTURE AND SYNTHESIS OF THE TERNARY ALKALI GRAPHITE-INTERCALATION COMPOUND KCSC16, AN IDEAL LAYERED HETEROSTRUCTURE
    HARK, SK
    YORK, BR
    SOLIN, SA
    JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (02): : 921 - 926
12345