Effects of surfactants on the molecular aggregation of squaraine dye Sq-2Me in aqueous solutions

被引:0
|
作者
Yefimova, S. L. [1 ]
Guralchuk, G. Ya [1 ]
Lebed, A. S. [1 ]
Sorokin, A., V [1 ]
Malyukin, Yu, V [1 ]
Kurilchertko, I. Yu [2 ]
机构
[1] Natl Acad Sci Ukraine, Inst Scintillat Mat, STC Inst Single Crystals, 60 Lenin Ave, UA-61001 Kharkov, Ukraine
[2] Slavyansk State Pedag Univ, Slavyansk, Donetsk Region, Ukraine
来源
FUNCTIONAL MATERIALS | 2009年 / 16卷 / 04期
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T [工业技术];
学科分类号
08 ;
摘要
The influence of anionic surfactant, sodium dodecyl sulphate (SDS), and cationic one, cetylpyridinium bromide (CPB), on aggregation behavior of squaraine dye Sq-2Me has been studied in aqueous solutions by optical spectroscopy. It has been found that the addition of surfactants at concentrations higher than critical micelle one into a DMF-W (95 %) solution does not prevent the dye aggregation. The structure of Sq-2Me aggregates formed in SDS and CPB micelles is discussed using the exciton theory. The results show that the optical properties and the Sq-2Me aggregate structure can be tuned using interaction with surfactant micelles of different nature.
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页码:460 / 465
页数:6
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