SYNTHESIS OF HEXAMERIC LIGNIN MODEL COMPOUNDS

被引：17

作者：

KILPELAINEN, I

TERVILAWILO, A

PERAKYLA, H

MATIKAINEN, J

BRUNOW, G

机构：

[1] UNIV HELSINKI,DEPT CHEM,SF-00014 HELSINKI,FINLAND

[2] UNIV HELSINKI,INST BIOTECHNOL,SF-00014 HELSINKI,FINLAND

[3] CULTOR LTD,CTR TECHNOL,SF-02460 KYRKSLATT,FINLAND

来源：

HOLZFORSCHUNG | 1994年 / 48卷 / 05期

关键词：

LIGNIN MODEL COMPOUNDS; BETA-ARYL ETHER; BIPHENYL; NMR;

D O I：

10.1515/hfsg.1994.48.5.381

中图分类号：

S7 [林业];

学科分类号：

0829 ; 0907 ;

摘要：

Three different hexameric lignin model compounds were synthesised. Two different synthesis routes were used to obtain trimeric lignin model compounds containing beta-aryl ether bonds. The trimers were dimerised using enzymatic oxidation to hexamers containing beta-O-4 and 5-5' bonds. The hexamers were characterised with H-1 and C-13 NMR spectroscopy as well as with mass spectrometry.

引用

页码：381 / 386

页数：6

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