SODIUM-SELECTIVE POLYMERIC MEMBRANE ELECTRODES BASED ON CALIX[4]ARENE DERIVATIVES

被引：7

作者：

Shibutani, Yasuhiko ^{[1
]}

Yakabe, Kenji ^{[1
]}

Shono, Toshiyuki ^{[1
]}

Yamashoji, Yuko ^{[2
]}

Tanaka, Minoru ^{[2
]}

机构：

[1] Osaka Inst Technol, Dept Appl Chem, Fac Engn, Asahi Ku, Osaka 535, Japan

[2] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 565, Japan

来源：

ANALYTICAL SCIENCES | 1991年 / 7卷

关键词：

Ion-selective membrane electrode; sodium ion assay; calix[4]arene; human blood serum;

D O I：

10.2116/analsci.7.Supple_1671

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Four kinds of lipophilic calix[4]aryl ester derivatives (A)-(D) have been designed for Na+-selective polymeric membrane electrodes. On the ion selectivity of (A)-based electrode, the phenyl ether type membrane solvent, especially FPNPE is superior to the diester type ones in Na+ selectivity against K+. On the contrary, in the Na+ electrode of (B), de-tert-butylated derivative of (A), the diester type solvent, DOP gave good result.,The selectivity coefficients for Na+ with respect to K+ (-log k(Nak)(Pot)) being nearly 2.5. The (B)/DOP-based Na+-selective electrode was successfully applied to Na+ assay in human blood sera.

引用

页码：1671 / 1674

页数：4

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