RING EXPANSION AND REARRANGEMENT REACTIONS OF N-HETEROARYLMETHYL RADICALS

被引：4

作者：

MCLELLAN, JF ^{[1
]}

MCNAB, H ^{[1
]}

MUIR, TW ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 10期

关键词：

D O I：

10.1039/c39930000839

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flash vacuum pyrolysis of N-(p-chlorophenoxymethyl)azoles (e.g. 2 and 3) gives ring expanded products (e.g. 4 and 8) formed via N-heteroarylmethyl radicals (e.g. 1 and 6); the mechanism of ring expansion generally involves a novel 'walk'-rearrangement of the radical centre.

引用

页码：839 / 840

页数：2

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