12-(2-Hydroxy-6-oxocyclohex-1-enyl)-9,10-dihydro-8H-benzo[a]xanthen-11(12H)-one

被引:1
|
作者
Akkurt, Mehmet [1 ]
Mohamed, Shaaban K. [2 ,3 ]
Kennedy, Alan R. [4 ]
Abdelhamid, Antar A. [5 ]
Miller, Gary J. [6 ]
Albayati, Mustafa R. [7 ]
机构
[1] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey
[2] Manchester Metropolitan Univ, Chem & Environm Div, Manchester M1 5GD, Lancs, England
[3] Menia Univ, Fac Sci, Dept Chem, El Minia 61519, Egypt
[4] Univ Strathclyde, Dept Pure Appl Chem, Glasgow G1 1XL, Lanark, Scotland
[5] Manchester Metropolitan Univ, Chem & Environm Div, Manchester M1 5GD, Lancs, England
[6] Manchester Metropolitan Univ, Analyt Sci, Manchester M1 5GD, Lancs, England
[7] Kirkuk Univ, Coll Sci, Dept Chem, Kirkuk, Iraq
关键词
D O I
10.1107/S1600536813025324
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the xanthenone system of the title compound, C23H20O4, the pyran ring has a maximum deviation of 0.111 (1) angstrom from planarity and the outer cyclohexene ring exhibits a puckered conformation. The three methylene C atoms of the cyclohexene ring bonded to the pyran unit are disordered over two sets of sites [occupancies = 0.570 (3) and 0.430 (3)]. In the crystal, molecules are linked by C-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, forming a two-dimensional network parallel to (110). A C-H center dot center dot center dot pi interaction occurs between these networks.
引用
收藏
页码:O1558 / U893
页数:12
相关论文
共 50 条
  • [31] 5,9,10-trihydroxy-2,2-dimethyl-12-(3-methyl-but-2-enyl)-2H,6H-pyrano[3,2-b]xanthen-6-one methanol solvate
    Chantrapromma, S
    Boonnak, N
    Fun, HK
    Anjum, S
    Rahman, A
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O2136 - O2138
  • [32] 1,3,9,11,12,14-HEXA-AZAPENTACENE-2,4,8,10(3H,9H,12H,14H)-TETRAONES (DOUBLED 5-DEAZAFLAVINS) WITH POTENTIAL FOR OXIDO REDUCTION
    YONEDA, F
    KOGA, M
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (07): : 1809 - 1812
  • [33] 2,3,4,9-Tetrahydro-9-(3-hydroxy-1,4-dioxo-1H-dihydro-naphthalen-2-yl)-8-methoxy-3,3-dimethyl-1H-xanthen-1-one
    Yoshioka, Eito
    Kohtani, Shigeru
    Miyabe, Hideto
    MOLBANK, 2015, (01)
  • [34] STRUCTURES OF 2 DIMERS FORMED FROM LOMATIN(9,10-DIHYDRO-9-HYDROXY-8,8-DIMETHYL-8H-BENZO[1,2-B=3,4-B']DIPYRAN-2-ONE)
    KAMAT, VS
    TRIVEDI, GK
    BHATTACHARYYA, SC
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1976, (17): : 1857 - 1861
  • [35] BIS(1A,8B-DIHYDRO(1,1-H-2(2))-2H-BENZO[A]CYCLOPROPA[C]CYCLOHEPTEN-2-ONE)HYDROGEN(I) HEXACHLOROANTIMONATE, [H(C12H8D2O)2][SBCL6]
    CHILDS, RF
    FAGGIANI, R
    LOCK, CJL
    VARADARAJAN, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (JUL) : 1291 - 1294
  • [36] 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en- 1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one
    Kurbanova, Malahat M.
    Gurbanov, Atash V.
    Mahmudov, Kamran T.
    Maharramov, Abel M.
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1606 - +
  • [37] The crystal structure of (R)-6-hydroxy-8-methoxy-3-methylisochroman-1-one, C11H12O4
    Li, Hong
    Lin, Can-Kai
    Huang, Rong-Chun
    Chen, Kai-Xin
    Liang, Hai-Xuan
    Cai, Yan-Jia
    Chen, Zi-Feng
    Tao, Yi-Wen
    Ding, Bo
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2022, 237 (04): : 741 - 743
  • [38] Bronsted acidic ionic liquids catalyzed the preparation of 13-aryl-5H-dibenzo[b,i]xanthene-5,7,12,14(13H)-tetraones and 3,4-dihydro-1H-benzo[b]xanthene-1,6,11(2H,12H)-triones
    Shaterian, Hamid Reza
    Sedghipour, Marziyeh
    Mollashahi, Ebrahim
    RESEARCH ON CHEMICAL INTERMEDIATES, 2014, 40 (04) : 1345 - 1355
  • [39] Brønsted acidic ionic liquids catalyzed the preparation of 13-aryl-5H-dibenzo[b,i]xanthene-5,7,12,14(13H)-tetraones and 3,4-dihydro-1H-benzo[b]xanthene-1,6,11(2H,12H)-triones
    Hamid Reza Shaterian
    Marziyeh Sedghipour
    Ebrahim Mollashahi
    Research on Chemical Intermediates, 2014, 40 : 1345 - 1355
  • [40] 7-Bromo-9-(2-hydroxy-4,4-dimethyl6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one
    Mohamed, Shaaban K.
    Akkurt, Mehmet
    Abdelhamid, Antar A.
    Fanwick, Phillip E.
    Potgeiterd, Herman
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1710 - +