High mechanical reinforcing efficiency of layered poly(vinyl alcohol) - graphene oxide nanocomposites

被引:22
|
作者
Sellam, Charline [1 ]
Zhai, Zhi [1 ]
Zahabi, Hediyeh [1 ]
Picot, Olivier T. [1 ]
Deng, Hua [2 ]
Fu, Qiang [2 ]
Bilotti, Emiliano [1 ]
Peijs, Ton [1 ]
机构
[1] Queen Mary Univ London, Sch Engn & Mat Sci, Mile End Rd, London E1 4NS, England
[2] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Sichuan, Peoples R China
关键词
Layer-by-layer; spray; nanocomposites; PVA; graphene oxide; hierarchical composites;
D O I
10.1179/2055033215Y.0000000001
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A bottom-up approach for producing poly(vinyl alcohol) (PVA)/graphene oxide (GO) nanocomposites using a spray-assisted layer-by-layer (LbL) method is presented. Simple and versatile, the process allows to build up uniform multi-layered nanocomposite films with good morphological control of each layer. A total of 150 bilayers were deposited to create a transparent film with improved mechanical properties at a loading of 5.4 wt% GO. The Young's modulus and tensile strength of these films nearly doubled as a result of the high level of structural organization of the nanocomposite incorporating the two-dimensional (2D) nanofiller, in combination with good interfacial interactions resulting from hydrogen bonding between PVA and the GO sheets.
引用
收藏
页码:89 / 95
页数:7
相关论文
共 50 条
  • [31] Enhanced Mechanical and Antibacterial Properties of Nanocomposites Based on Poly(vinyl Alcohol) and Biopolymer-Derived Reduced Graphene Oxide
    Cho, Beom-Gon
    Joshi, Shalik Ram
    Lee, Seongjin
    Kim, Shin-Kwan
    Park, Young-Bin
    Kim, Gun-Ho
    POLYMERS, 2021, 13 (04) : 1 - 17
  • [32] Mechanical Properties of Poly(vinyl alcohol) Montmorillonite Nanocomposites
    Soundararajah, Q. Y.
    Karunaratne, B. S. B.
    Rajapakse, R. M. G.
    JOURNAL OF COMPOSITE MATERIALS, 2010, 44 (03) : 303 - 311
  • [33] The synthesis of graphene nanoribbon and its reinforcing effect on poly (vinyl alcohol)
    Shang, Songmin
    Gan, Lu
    Yuen, Chun Wah Marcus
    Jiang, Shou-xiang
    Luo, Nicy Mei
    COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2015, 68 : 149 - 154
  • [34] Enhanced tensile strength and initial modulus of poly(vinyl alcohol)/graphene oxide composite fibers via blending poly(vinyl alcohol) with poly(vinyl alcohol)-grafted graphene oxide
    Zhang, Shengchang
    Liu, Pengqing
    Zhao, Xiangsen
    Xu, Jianjun
    JOURNAL OF POLYMER RESEARCH, 2018, 25 (03)
  • [35] Enhanced tensile strength and initial modulus of poly(vinyl alcohol)/graphene oxide composite fibers via blending poly(vinyl alcohol) with poly(vinyl alcohol)-grafted graphene oxide
    Shengchang Zhang
    Pengqing Liu
    Xiangsen Zhao
    Jianjun Xu
    Journal of Polymer Research, 2018, 25
  • [36] Antimicrobial Films Based on Nanocomposites of Chitosan/Poly(vinyl alcohol)/Graphene Oxide for Biomedical Applications
    Ruiz, Sebastian
    Andres Tamayo, Julian
    Delgado Ospina, Johannes
    Navia Porras, Diana Paola
    Valencia Zapata, Mayra Eliana
    Mina Hernandez, Jose Herminsul
    Humberto Valencia, Carlos
    Zuluaga, Fabio
    Grande Tovar, Carlos David
    BIOMOLECULES, 2019, 9 (03)
  • [37] Microwave radiations effect on electrical and mechanical properties of poly (vinyl alcohol) and PVA/graphene nanocomposites
    Afzal, Hafiz Muhammad
    Mitu, Sheikh Sharif Iqbal
    Al-Harthi, Mamdouh A.
    SURFACES AND INTERFACES, 2018, 13 : 65 - 78
  • [38] Biocompatible and Antimicrobial Electrospun Membranes Based on Nanocomposites of Chitosan/Poly (Vinyl Alcohol)/Graphene Oxide
    Tamayo Marin, Julian Andres
    Ruiz Londono, Sebastian
    Delgado, Johannes
    Navia Porras, Diana Paola
    Valencia Zapata, Mayra Eliana
    Mina Hernandez, Jose Herminsul
    Humberto Valencia, Carlos
    Grande Tovar, Carlos David
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2019, 20 (12):
  • [39] Poly(vinyl alcohol) nanocomposites based on graphene and graphite oxide: a comparative investigation of property and mechanism
    Bao, Chenlu
    Guo, Yuqiang
    Song, Lei
    Hu, Yuan
    JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (36) : 13942 - 13950
  • [40] Poly(vinyl alcohol)/graphene oxide nanocomposites prepared by in situ polymerization with enhanced mechanical properties and water vapor barrier properties
    Ma, Jiaojiao
    Li, Ying
    Yin, Xiande
    Xu, Yu
    Yue, Jia
    Bao, Jianjun
    Zhou, Tao
    RSC ADVANCES, 2016, 6 (55) : 49448 - 49458