SYNTHETIC DESIGN OF FERRIMAGNETIC MATERIALS - ONE-DIMENSIONAL BIMETALLIC COORDINATION POLYMERS

被引:0
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作者
WILLETT, RD
WANG, ZM
MOLNAR, S
BREWER, K
LANDEE, CP
TURNBULL, MM
ZHANG, WR
机构
[1] CLARK UNIV,DEPT PHYS,WORCESTER,MA 01610
[2] CLARK UNIV,DEPT CHEM,WORCESTER,MA 01610
[3] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An approach to the synthesis of altemating site linear chain systems using cationic bricks containing Cu(II) ions and anionic mortar is described. Bricks formed with neutral quadradentate N4 macrocycles successfully permit the construction of ordered bimetallic chains, although the magnetic interactions are always found to be weak. Efforts to form similar systems using mono- or bi-dentate neutral ligands have thus far failed to lead to the assembly of the desired structures.
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页码:637 / 642
页数:6
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