AN UNUSUAL ACCESS TO 4,5-BIS(ALKYLIDENE)-1,3-DITHIOLAN-2-ONES - A NEW CLASS OF CISOID DIENES

被引：20
|
作者：
BOIVIN, J [1 ]
TAILHAN, C [1 ]
ZARD, SZ [1 ]
机构：
[1] ECOLE POLYTECH,CNRS,SYNTH ORGAN LAB,F-91128 PALAISEAU,FRANCE
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 51期
关键词：
D O I：
10.1016/S0040-4039(00)74761-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Upon heating in chlorobenzene, propargylic xanthates 1b & 1c give the corresponding 4,5-bis(alkylidene)-1,3-dithiolan-2-one 6 which is captured in situ by a dienophile 4 to give the Diels Alder adduct 7.
引用
收藏
页码：7853 / 7856
页数：4
相关论文
共 50 条
  • [21] MASS-SPECTROMETRY IN ISOMER DIFFERENTIATION - 4,5-BIS(ALKYLTHIO)-1,3-DITHIOL-2-ONES AND 1,2-DITHIOL-3-ONES
    ANDREU, R
    GAYAN, I
    GARIN, J
    ORDUNA, J
    SAVIRON, M
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1994, 8 (06) : 455 - 458
  • [22] 9-[4,5-Bis(benzylsulfanyl)-1,3-dithiol-2-ylidene]-4,5-diazafluorene
    Zhong, Xu-Dong
    Zhu, Yu-Lan
    Wu, Xue
    Jin, Jing-Yi
    Tang, Xue-Ling
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1353 - U2702
  • [23] 4,5-Bis(fluorodinitromethyl)-2-methoxy-1,3-dioxolane
    Corbett, JM
    Dickman, MH
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 1851 - 1853
  • [24] Syntheses, crystal structures and DFT calculations of 2-[4,5-bis(ethylsulfanyl)-1,3-dithiol-2-ylidene]-5-(4,5-diiodo-1, 3-dithiol-2-ylidene)-1,3-dithiolan-4-thione and -one
    Ueda, K.
    Suzuki, K.
    Suzuki, K.
    Yoza, K.
    Ishida, T.
    PHYSICA B-CONDENSED MATTER, 2010, 405 (11) : S69 - S74
  • [25] 4,5-Bis(arylethynyl)-1,2,3-triazoles-A New Class of Fluorescent Labels: Synthesis and Applications
    Govdi, Anastasia, I
    Tokareva, Polina, V
    Rumyantsev, Andrey M.
    Panov, Maxim S.
    Stellmacher, Johannes
    Alexiev, Ulrike
    Danilkina, Natalia A.
    Balova, Irina A.
    MOLECULES, 2022, 27 (10):
  • [26] Cyclization of 1,3-dialkyl-4,5-bis(1-thiosemicarbazido)imidazolidin-2-ones(thiones) with aromatic aldehydes
    Gazieva, Galina A.
    Vasilevskii, Sergei V.
    Belyakov, Pavel A.
    Nelyubina, Yulia V.
    Lubuzh, Elena D.
    Kravehenko, Angelina N.
    MENDELEEV COMMUNICATIONS, 2010, 20 (05) : 285 - 287
  • [27] 2-[4,5-bis(n-pentylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiolo[4,5-c]pyrrole
    Nielsen, KA
    Bond, AD
    Jeppesen, JO
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O1702 - O1703
  • [28] Thione vs. ketone: The influence of the chalcogenide on weak intermolecular interactions in crystal packing of 4,5-bis(bromomethyl)-1,3-dithiole-2-thione and 4,5-bis(bromomethyl)-1,3-dithiol-2-one
    Azov, Vladimir A.
    Zeller, Matthias
    Watat, Michele-Laure Lieunang
    Xin, Ying
    JOURNAL OF MOLECULAR STRUCTURE, 2011, 1004 (1-3) : 296 - 302
  • [29] Ethyl 2-[4,5-bis(butylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiolo[4,5-c]pyrrole-4-carboxylate
    Li, Dong-Feng
    Zhu, Xiao-Fei
    Guan, Shuang
    Hou, Rui-Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1400 - +
  • [30] Synthesis　and　Structure　of　4，5－bis（2，4－Dinitrophenylthio）－1，3－Dithiole－2－Thione
    Qu Zheng
    Cai Jing-Hua
    Fang Qi
    You Xiao-Zeng(Coordination Chemistry Instzjute
    结构化学, 1995, (04) : 318 - 320
12345