ELECTRONIC RELAXATION OF THE 4T2 STATE OF CHROMIUM(III) IN BIGAZYT FLUORIDE GLASSES

被引:13
|
作者
FERNANDEZ, J
ILLARRAMENDI, MA
BALDA, R
ARRIANDIAGA, MA
LUCAS, J
ADAM, JL
机构
[1] UNIV BASQUE COUNTRY, FAC CIENCIAS, DEPT FIS APLICADA 2, BILBAO, SPAIN
[2] UNIV RENNES 1, CHIM MINERALE LAB D, F-35042 RENNES, FRANCE
关键词
Gallium Compounds - Concentration - Relaxation Processes;
D O I
10.1016/0022-3093(91)90760-4
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Optical properties of the Cr3+ ion in heavy-metal fluoride BIGaZYT glasses with different gallium concentrations are presented. Analysis of the spectroscopic data together with the time evolution of emission spectra allow for the assumption of two distinguishable distributions of Cr3+ sites in these glasses. Site distribution and quantum efficiency are found to be a function of gallium concentration.
引用
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页码:1230 / 1234
页数:5
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