THE FORMATION AND PHOTOLYSIS OF TANTALUM SULFIDE CLUSTER IONS

被引:0
|
作者
ZHANG, N [1 ]
YU, ZD [1 ]
WU, XJ [1 ]
GAO, Z [1 ]
ZHU, QH [1 ]
KONG, FN [1 ]
机构
[1] CHINESE ACAD SCI,INST CHEM,MOLEC REACT DYNAM LAB,BEIJING 100080,PEOPLES R CHINA
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中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Tantalum sulfide cluster ions were produced by direct laser ablation, and were studied with a tandem time-of-flight mass spectrometer. The main dissociation channel of the UV-photolysis (248 nm) of tantalum sulfide cluster ions is sequent S2 loss. Structures with Ta3S4 and Ta4S6 as frameworks were suggested for the large tantalum sulfide cluster ions.
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页码:S246 / S248
页数:3
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