COORDINATION-COMPOUNDS OF 2-HYDROXY-4,6-DIPHENYL-THIOBENZOPHENONE - CHELATE COMPLEXES OF COBALT AND NICKEL, X-RAY STRUCTURE OF THE NICKEL COMPOUND

被引：4
|
作者：
LORENZ, B
ZIMMERMANN, T
HUBENER, R
ABRAM, U
机构：
[1] UNIV TUBINGEN,INST ANORGAN CHEM,AUF DER MORGENSTELLE 18,D-72076 TUBINGEN,GERMANY
[2] KAI EV,WIP,D-04318 LEIPZIG,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 11期
关键词：
COBALT COMPLEXES; NICKEL COMPLEXES; X-RAY DIFFRACTION; MONOTHIO-BETA-DIKETONATO CHELATES;
D O I：
10.1002/zaac.19936191114
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
2-Hydroxy-4,6-diphenyl-thiobenzophenone (HL) reacts under deprotonation with metal salts to chelate complexes. The reactions with nickel acetate or cobalt acetate yield neutral complexes of the composition NiL2 and CoL3, respectively. The nickel compound crystallizes monoclinic in the space group P2(1)/c (No. 14), a = 17.55(6), b = 26.69(4), c = 8.49(9) angstrom, beta = 102.7(2)-degrees, Z = 4. The nickel atom has a distorted square-planar coordination sphere. The ligands are cis coordinated.
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页码：1905 / 1908
页数：4
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