ELECTROSORPTION OF NORMAL-BUTANOL ON MERCURY FROM CONCENTRATED AQUEOUS KCL AND HCL SOLUTIONS - A STUDY IN SALTING-OUT AND SALTING-IN EFFECTS

被引：2

作者：

BAIKERIKAR, KG ^{[1
]}

HANSEN, RS ^{[1
]}

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1987年 / 120卷 / 01期

关键词：

MERCURY AND AMALGAMS - Adsorption;

D O I：

10.1016/0021-9797(87)90339-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of n-butanol was studied from 2 M HCl and 2 M KCl solutions by electrocapillary and double-layer capacity measurements. n-Butanol and other aliphatic alcohols are salted out from KCl and other salt solutions but are interestingly salted in from solutions of HCl and other acids. Anomalous capacity behavior of n-butanol was evident from HCl solutions. The result is explained as arising from the penetration of the electrolyte into the surface film.

引用

页码：189 / 194

页数：6

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