Novel polymer metal complexes as precursors for electroluminescent materials

被引：0
|
作者：
Savchenko, I [1 ]
Bereznitskaya, A. [2 ]
Smola, S. [3 ]
Fedorov, Ya [2 ]
Ivaha, N. [2 ]
机构：
[1] Kyiv Natl TShevehenko Univ, 60 Volodymyrska Str, UA-01033 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, V Vernadsky Inst Gen & Inorgan Chem, UA-03142 Kiev, Ukraine
[3] Natl Acad Sci Ukraine, A Bogatsky Phys Chem Inst, UA-65080 Odessa, Ukraine
来源：
FUNCTIONAL MATERIALS | 2012年 / 19卷 / 04期
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D O I：
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中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The monomer - 2 methyl-5-phenylpentene-1-dione-3,5, their complexes with Nd(III), Eu(III), Er(III), new metallopolymers based of them are obtained. Structure of the monomer, the metal complexes and the metallopolymers confirmed by the data of NMR-, electronic, diffusion and infrared spectroscopes, elemental and termogravimetric analysis. The luminescent spectra of the obtained metallocomplexes and polycomplexes in solutions, films and solid state have been investigated and analyzed. The luminescence quantum yield of polycomplex based Eu(III) is maximal. The obtained polymetallocomplexes can be used as potential materials for organic light-emitting devices.
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页码：551 / 557
页数：7
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