AN EXTREMELY EFFICIENT SYNTHESIS OF THIOPHENE 1,1-DIOXIDES - OXIDATION OF THIOPHENE DERIVATIVES WITH DIMETHYLDIOXIRANE

被引：41
|
作者：
MIYAHARA, Y
INAZU, T
机构：
[1] Department of Chemistry, Faculty of Science, Kyushu University 33 Hakozaki, Higashi-ku, Fukuoka
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 41期
关键词：
D O I：
10.1016/S0040-4039(00)98003-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Dimethyldioxirane was found to oxidize electron-rich thiophene derivatives, including sterically hindered thiophenophanes, to the corresponding thiophene 1,1-dioxides in excellent yields. Electronwithdrawing groups on a thiophene ring substantially retarded the oxidation, but dimethyldioxitane remained superior to other reagents. © 1990.
引用
收藏
页码：5955 / 5958
页数：4
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