FACILE INTRODUCTION OF N-15 INTO CHALCOGEN NITROGEN SYSTEMS USING N-15-LABELED AMMONIA

被引：14

作者：

GINN, VC ^{[1
]}

KELLY, PF ^{[1
]}

WOOLLINS, JD ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,S KENSINGTON,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 13期

关键词：

D O I：

10.1039/dt9920002129

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of N-15-labelled ammonia with a toluene solution of (EtO)2SeO under reduced pressure gives (Se4N4)-N-15; in the presence of [PtCl2(PMe2Ph)2] (with CH2Cl2 as solvent) the same reagents yield [Pt(Se2N2)-N-15 (PMe2Ph)2] whilst (NH3)-N-15, [PtCl2(PMe2Ph)2] and SOCl2 react to form [Pt(NSO)2)-N-15-(PMe2Ph)2].

引用

页码：2129 / 2130

页数：2

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