SYNTHESIS AND CHARACTERIZATION OF SOME BIVALENT TRANSITION-METAL COMPLEXES WITH ACETYLACETONE MONO-BENZOYLHYDRAZONE AND ACETYLACETONE MONO-ISONICOTINOYLHYDRAZONE

被引：1

作者：

NARANG, KK

SINGH, VP

机构：

[1] Department of Chemistry, Banaras Hindu University

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 06期

关键词：

D O I：

10.1080/00945719408001309

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Acetylacetone mono-benzoylhydrazone, PhCONHN = C(Me)CH2C(Me)O (LH) ,and acetylacetone mono-isonicotinoylhydrazone, NC5H4CONHN = C(Me)CH2C(Me)O (L 'H) , complexes of the type [ML2] and [ML2'] (M = Co(II), Ni(II), Cu(II) or Zn(II)) have been Prepared and characterized. The ligands form monobasic, four-coordinate complexes and chelate via enolate and imine. The E.S.R. spectra of the Cu(II) complexes suggest a square coplanar stereochemistry.

引用

页码：891 / 904

页数：14

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