CHIRAL RECOGNITION OF OLEFINS BY H-1-NMR SPECTROSCOPY IN THE PRESENCE OF A CHIRAL DIRHODIUM COMPLEX

被引：67

作者：

WYPCHLO, K ^{[1
]}

DUDDECK, H ^{[1
]}

机构：

[1] UNIV HANNOVER,INST ORGAN CHEM,D-30167 HANNOVER,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 01期

关键词：

D O I：

10.1016/S0957-4166(00)80477-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new NMR method using 1 for chiral recognition of olefins is presented and compared with Mannschreck's method using Yb(hfc)(3)/Ag(fod). It was found that the spectroscopic results are comparable but the new rhodium reagent is much easier to handle and can readily be recovered. [GRAPHICS] ty.

引用

页码：27 / 30

页数：4

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