STRAIGHTFORWARD SYNTHESIS AND REACTIVITY OF POLYMER-SUPPORTED ORGANOTIN HYDRIDES

被引：0
|
作者：
DUMARTIN, G
RUEL, G
KHARBOUTLI, J
DELMOND, B
CONNIL, MF
JOUSSEAUME, B
PEREYRE, M
机构：
来源：
SYNLETT | 1994年 / 11期
关键词：
POLYMER-SUPPORTED; ORGANOTIN HYDRIDES; HYDRIDODIBUTYLSTANNYLLITHIUM; POLLUTION;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Polymer-supported organotin hydrides were prepared by the reaction of omega-haloalkylpolystyrenes with hydridodibutylstannyllithium. The stannyl group was separated from the phenyl ring by a two-, three- or four carbon spacer. These polymers were found to contain 0.8 to 1.4 mmole SnH per gram. The reducing ability of the polymer-supported organotin hydrides was monitored by reaction with haloalkanes. The amount of organotin residues was estimated.
引用
收藏
页码：952 / 954
页数：3
相关论文
共 50 条
  • [1] POLYMER-SUPPORTED ORGANOTIN HYDRIDES AS IMMOBILIZED REAGENTS FOR FREE-RADICAL SYNTHESIS
    GERIGK, U
    GERLACH, M
    NEUMANN, WP
    VIELER, R
    WEINTRITT, V
    [J]. SYNTHESIS-STUTTGART, 1990, (06): : 448 - 452
  • [2] In situ generated, polymer-supported organotin hydrides as clean reducing agents
    Dumartin, G
    Pourcel, M
    Delmond, B
    Donard, O
    Pereyre, M
    [J]. TETRAHEDRON LETTERS, 1998, 39 (26) : 4663 - 4666
  • [3] Preparation and reactivity of a macroporous polymer-supported organotin hydride catalyst
    Chemin, A
    Deleuze, H
    Maillard, B
    [J]. EUROPEAN POLYMER JOURNAL, 1998, 34 (10) : 1395 - 1404
  • [4] Preparation and reactivity of a non-styrenic polymer-supported organotin chloride catalyst
    Chemin, A
    Deleuze, H
    Maillard, B
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (02): : 137 - 142
  • [5] POLYMER-SUPPORTED ORGANOTIN HYDRIDES - ARE THEY USEFUL FOR CARBON-CARBON BOND-FORMING REACTIONS
    HERSHBERGER, J
    WHITE, W
    BEADLE, L
    PIKE, P
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 298 - ORGN
  • [6] Polymer-supported organotin reagents in the catalytic Stille reaction
    Hernan, AG
    Guillot, V
    Kuvshinov, A
    Kilburn, JD
    [J]. TETRAHEDRON LETTERS, 2003, 44 (47) : 8601 - 8603
  • [7] A POLYMER-SUPPORTED ORGANOTIN HYDRIDE AND ITS MULTIPURPOSE APPLICATION IN RADICAL ORGANIC-SYNTHESIS
    GERLACH, M
    JORDENS, F
    KUHN, H
    NEUMANN, WP
    PETERSEIM, M
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (21): : 5971 - 5972
  • [8] SYNTHESIS AND REACTIVITY OF POLYMER-SUPPORTED REDUCING AGENTS WITH CHEMICALLY MODIFIED SURFACES
    MENGER, FM
    SHINOZAKI, H
    LEE, HC
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (13): : 2724 - 2725
  • [9] Polymer-supported synthesis of oligosaccharides
    Krepinsky, JJ
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 3 - ORGN
  • [10] Polymer-supported organotin reagents for regioselective halogenation of aromatic amines
    Chrétien, JM
    Zammattio, F
    Le Grognec, E
    Paris, M
    Cahingt, B
    Montavon, G
    Quintard, JP
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (07): : 2870 - 2873
12345