A NEW, ONE-POT (E)-STEREOSELECTIVE SYNTHESIS OF RACEMIC AND CHIRAL ALPHA,BETA-UNSATURATED SULFOXIDES FROM SULFINATES AND LITHIUM DIMETHYLDIPHENYLPHOSPHONIUM DIYLIDE

被引：0

作者：

MIKOLAJCZYK, M ^{[1
]}

PERLIKOWSKA, W ^{[1
]}

OMELANCZUK, J ^{[1
]}

CRISTAU, HJ ^{[1
]}

PERRAUDDARCY, A ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM,CHIM ORGAN LAB,F-34053 MONTPELLIER,FRANCE

来源：

SYNLETT | 1991年 / 12期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha,beta-Unsaturated sulfoxides 6 with (E)-geometry, both racemic or optically active, were effectively synthesized by the one-pot reaction of lithium dimethyldiphenylphosphonium diylide [1; lithiomethyl(methylene)diphenylphosphorane] with sulfinates 2 followed by treatment of the alpha-sulfinylmethylmethyldiphenylphosphonium ylide formed [4; methyldiphenyl(sulfinylmethylene)phosphorane] with aldehydes.

引用

页码：913 / 915

页数：3

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