SYNTHESIS AND SPECTRAL STUDY OF SEVERAL SOLID M3[EU(2,6-PYRIDINEDICARBOXYLATE)3] SALTS (M = LI+, NA+, K+, RB+, CS+, NH4+, AND PYRIDINIUM+)

被引：14
|
作者：
STUMP, NA
SCHWEITZER, GK
PESTERFIELD, LL
PETERSON, JR
MURRAY, GM
机构：
[1] UNIV MARYLAND,DEPT CHEM,CATONSVILLE,MD 21228
[2] WESTERN KENTUCKY UNIV,DEPT CHEM,BOWLING GREEN,KY 42101
[3] OAK RIDGE NATL LAB,DIV CHEM,TRANSURANIUM RES LAB,OAK RIDGE,TN 37831
来源：
SPECTROSCOPY LETTERS | 1992年 / 25卷 / 08期
关键词：
EU-3+ LUMINESCENCE; 2,6-PYRIDINEDICARBOXYLATE; COUNTERION EFFECT;
D O I：
10.1080/00387019208017874
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Salts of the [Eu(2,6-pyridinedicarboxylate)3]3- complex anion and various monovalent inorganic and organic counterions (Li+, Na+, K+, Rb+, Cs+, NH4+, and pyridinium+) have been synthesized and studied by emission spectroscopy. The Eu3+ ion emission spectra exhibited by these salts have been observed with high resolution (less than 1.0 cm-1) and at low temperature (77 K). The emission spectra of these compounds indicate that changing the attached counterion does not affect the site symmetry observed by the europium ion beyond slight distortions indicated by small shifts in the energies of the Eu3+, electronic levels.
引用
收藏
页码：1421 / 1432
页数：12
相关论文
共 50 条
  • [1] Superprotonic conductivity in MH(PO3H) (M=Li+, Na+, K+, Rb+, Cs+, NH4+)
    Zhou, Weihua
    Bondarenko, Alexander S.
    Boukamp, Bernard A.
    Bouwmeester, Henny J. M.
    SOLID STATE IONICS, 2008, 179 (11-12) : 380 - 384
  • [2] Mesophases and Ionic Conductivities of Simple Organic Salts of M(m-lodobenzoate) (M = Li+, Na+, K+, Rb+, and Cs+)
    Endo, Manami
    Nakane, Yuta
    Takahashi, Kiyonori
    Hoshino, Norihisa
    Takeda, Takashi
    Noro, Shin-ichiro
    Nakamura, Takayoshi
    Akutagawa, Tomoyuki
    JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (04): : 1768 - 1777
  • [3] Chabazite structures with Li+, Na+, Ag+, K+, NH4+, Rb+ and Cs+ as extra-framework cations
    Kong, Mihye
    Liu, Zhenxian
    Vogt, Thomas
    Lee, Yongjae
    MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 221 : 253 - 263
  • [4] SELECTIVITY OF CRYSTALLINE CEIV PHOSPHATE SULFATE HYDRATES FOR LI+, NA+, K+, RB+ CS+, AND NH4+ IN ABSOLUTE METHANOL AND ABSOLUTE DIMETHYLSULFOXIDE
    KONIG, KH
    PSOTTA, L
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1978, 444 (SEP): : 243 - 248
  • [5] Crystal Structures and Physical Properties of (M+)(Crown Ethers)x(TCNQ)y Salts with M+ = Li+, Na+, K+, Rb+, and Cs+
    Sambe, Kohei
    Hoshino, Norihisa
    Takeda, Takashi
    Nakamura, Takayoshi
    Akutagawa, Tomoyuki
    CRYSTAL GROWTH & DESIGN, 2021, 21 (10) : 5928 - 5942
  • [6] SELECTIVITY OF CRYSTALLINE CE(IV) PHOSPHATE-SULFATE HYDRATES FOR LI+, NA+, K+, RB+, CS+, AND NH4+ IN AQUEOUS-MEDIUM
    KONIG, KH
    PSOTTA, L
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1978, 443 (AUG): : 212 - 216
  • [7] State of uranyl arsenates MIAsUO6•nH2O (MI-H+, Li+, Na+, K+, Rb+, Cs+, NH4+) in aqueous solution
    Nipruk, Oxana V.
    Chernorukov, Nikolay G.
    Elipasheva, Elena V.
    Klinshova, Kseniya A.
    Bakhmetev, Maxim O.
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2020, 324 (01) : 233 - 244
  • [8] State of uranyl arsenates MIAsUO6·nH2O (MI–H+, Li+, Na+, K+, Rb+, Cs+, NH4+) in aqueous solution
    Oxana V. Nipruk
    Nikolay G. Chernorukov
    Elena V. Elipasheva
    Kseniya A. Klinshova
    Maxim O. Bakhmetev
    Journal of Radioanalytical and Nuclear Chemistry, 2020, 324 : 233 - 244
  • [9] Metal-stabilized rare tautomers:: N4 metalated cytosine (M = Li+, Na+, K+, Rb+ and Cs+), theoretical views
    Monajjemi, M
    Ghiasi, R
    Sadjadi, MAS
    APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (08) : 635 - 640
  • [10] Raman spectra of the double-anion salts M3ZnCl4NO3 (M+ = K+, Rb+, NH4+)
    Carter, RL
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2000, 56 (12) : 2351 - 2363
12345