KINETICS OF CYCLOPENTENE EPOXIDATION BY CUMENE HYDROPEROXIDE

被引：0
|
作者：
Rybina, G. V. [1 ]
Meshechkina, A. E. [1 ]
Mel'nik, L. V. [1 ]
Srednev, S. S. [1 ]
Moskvichev, Yu. A. [1 ]
机构：
[1] Yaroslavl State Tech Univ, Yaroslavl, Russia
来源：
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA | 2012年 / 55卷 / 10期
关键词：
cyclopentene; cumene hydroperoxide; oxidation; kinetics; reaction rate constant; dissociation constants; inhibition; kinetic mode;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Kinetic regularities of hydroperoxide epoxidation of cyclopentene were studied. The kinetic model of reaction was proposed. The activation energy, the dissociation constant of the intermediate complexes and the reaction rate constants were determined. This model describes adequately the experimental data on the cyclopentene oxidation by cumene hydroperoxide.
引用
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页码：48 / +
页数：5
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