NUCLEOPHILIC AROMATIC-SUBSTITUTION REACTIONS OF 1-METHOXY-2-(DIPHENYLPHOSPHINYL)NAPHTHALENE WITH C-NUCLEOPHILE, N-NUCLEOPHILE, AND O-NUCLEOPHILE - FACILE SYNTHESIS OF DIPHENYL(1-SUBSTITUTED-2-NAPHTHYL)PHOSPHINES

被引：0

作者：

HATTORI, T

SAKAMOTO, J

HAYASHIZAKA, N

MIYANO, S

机构：

[1] TOHOKU UNIV,FAC ENGN,DEPT BIOCHEM & ENGN,AOBA KU,SENDAI 980,JAPAN

[2] SUMITOM SEIKA CHEM CO LTD,HYOGO 67501,JAPAN

来源：

SYNTHESIS-STUTTGART | 1994年 / 02期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel nucleophilic aromatic substitution reaction is described in which the methoxy group of 1-methoxy-2-(diphenylphosphinyl)-naphthalene is readily replaced with Grignard reagents, alkoxides, and amides. Reduction of the resulting phosphine oxides provides a convenient route to diphenyl(1-substituted-2-naphthyl)phosphines.

引用

页码：199 / 202

页数：4

共 7 条

[1] THE REACTIONS OF 2,2,2-TRICHLORO-1-PHENYLETHANONE WITH O-NUCLEOPHILE, C-NUCLEOPHILE AND S-NUCLEOPHILE
HESS, SC
NOME, F
ZUCCO, C
REZENDE, MC
SYNTHETIC COMMUNICATIONS, 1989, 19 (17) : 3037 - 3045
[2] HETEROCYCLIC 12-PI-SYSTEM AND 14-PI-SYSTEM .10. REACTIVITY OF 2-(METHYLTHIO)NAPHTHO[1,8-BE]-THIOLIUM TETRAFLUOROBORATE (PSEUDOPHENALENIUM SALT) TOWARDS C-NUCLEOPHILE AND N-NUCLEOPHILE
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SALZL, MH
JUSTUS LIEBIGS ANNALEN DER CHEMIE, 1977, (11-1): : 1938 - 1946
[3] FACILE SYNTHESIS OF 1,1'-BINAPHTHYL-2-CARBOXYLATES VIA NUCLEOPHILIC AROMATIC-SUBSTITUTION OF 1-METHOXY-2-NAPHTHOIC ESTERS BY 1-NAPHTHYL GRIGNARD-REAGENTS
HOTTA, H
SUZUKI, T
MIYANO, S
CHEMISTRY LETTERS, 1990, (01) : 143 - 144
[4] Nucleophilic substitution reactions of 1-halogeno-4-COR-2-nitrobenzenes and 1-halogeno-6-COR-2-nitrobenzenes with sodium benzenethiolate and piperidine. Can an ''inverted built-in solvation'' be responsible for the peculiar activation by an o-carboxamido group in SNAr reactions with an anionic nucleophile?
Arnone, C
Consiglio, G
Frenna, V
Spinelli, D
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (10): : 3093 - 3097
[5] Nucleophilic Substitution Reactions of 1-Halogeno-4-COR-2-nitrobenzenes and 1-Halogeno-6-COR-2-nitrobenzenes with Sodium Benzenethiolate and Piperidine. Can an Inverted Built-In Solvation Be Responsible for the Peculiar Activation by an o-Carboxamido Group in SNAr Reactions with an Anionic Nucleophile?
Arnone, C.
Consiglio, G.
Frenna, V.
Spinelli, D.
Journal of Organic Chemistry, 62 (10):
[6] Aromatic nucleophilic N-N, N-S and N-O exchange reactions of N,N-dimethyl-2-trifluoroacetyl-4-halo-1-naphthylamines with various amines, thiols and alcohols:: A facile synthesis of 2-trifluoroacetyl-4-halo-1-naphthylamines, sulfides and ethers
Okada, E
Tsukushi, N
Otsuki, Y
Nishiyama, S
Fukuda, T
SYNLETT, 1999, (01) : 126 - 128
[7] AROMATIC NUCLEOPHILIC N,S-EXCHANGE AND N,O-EXCHANGE REACTIONS OF N,N-DIMETHYL-2,4-BISTRIFLUOROACETYL-1-NAPHTHYLAMINE WITH VARIOUS THIOLS AND ALCOHOLS - A FACILE SYNTHETIC METHOD FOR ALKYL AND ARYL 1-[2,4-BIS(TRIFLUOROACETYL)NAPHTHYL] SULFIDES AND ETHERS
HOJO, M
MASUDA, R
OKADA, E
MIYA, H
SYNTHESIS-STUTTGART, 1989, (11): : 870 - 873

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