SYNTHESIS AND CHARACTERIZATION OF PP-G-BUTYL ACRYLATE COPOLYMERS

被引：19
|
作者：
SATHE, SN [1 ]
SRINIVASARAO, GS [1 ]
DEVI, S [1 ]
机构：
[1] MAHARAJA SAYAJIRAO UNIV BARODA,FAC SCI,DEPT CHEM,BARODA 390002,GUJARAT,INDIA
来源：
POLYMER INTERNATIONAL | 1993年 / 32卷 / 03期
关键词：
BUTYL ACRYLATE; ISOTACTIC POLYPROPYLENE; PERCENT GRAFTING; GRAFTING EFFICIENCY; VISCOSITY;
D O I：
10.1002/pi.4990320304
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Butyl acrylate was grafted onto isotactic polypropylene using benzoyl peroxide as an initiator and toluene as a solvent. Effects of various parameters such as monomer and initiator concentration, reaction time and temperature on rates of polymerization, percentage grafting and grafting efficiency were studied. The extent of grafting achieved was 2-85%. The graft copolymers were characterized by IR, thermal, viscometric and contact-angle studies. Improved thermal stability and decreased intrinsic viscosity and critical surface tension were observed for graft copolymers.
引用
收藏
页码：233 / 239
页数：7
相关论文
共 50 条
  • [1] Synthesis and characterization of maleic acid-butyl acrylate copolymers
    Chauhan, Asha
    ASIAN JOURNAL OF CHEMISTRY, 2007, 19 (01) : 155 - 158
  • [2] SYNTHESIS AND CHARACTERIZATION OF HDPE-G-BUTYL ACRYLATE
    RAVAL, H
    SINGH, YP
    MEHTA, MH
    DEVI, S
    POLYMER INTERNATIONAL, 1992, 29 (04) : 261 - 264
  • [3] Synthesis, characterization, and pressure-sensitive properties of butyl acrylate and methyl acrylate copolymers
    Wang, Chiliang
    Wang, Li
    Chen, Chang
    Chen, Tao
    Jiang, Guohua
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 101 (03) : 1535 - 1542
  • [4] Synthesis and characterization of poly(ethylene-vinyl alcohol)-g-poly(butyl acrylate) copolymers
    Azam, M.
    Dawkins, John V.
    E-POLYMERS, 2008,
  • [5] Synthesis and characterization of functional gradient copolymers of glycidyl methacrylate and butyl acrylate
    Fernandez-Garcia, Marta
    Canamero, Pedro Francisco
    de la Fuente, Jose Luis
    REACTIVE & FUNCTIONAL POLYMERS, 2008, 68 (09): : 1384 - 1391
  • [6] Synthesis and characterization of functional gradient copolymers of allyl methacrylate and butyl acrylate
    Paris, Rodrigo
    De La Fuente, Jose Luis
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (18) : 5304 - 5315
  • [7] Synthesis and characterization of reactive graft copolymers of poly(butyl acrylate) and cellulose
    Chauhan, GS
    Singh, B
    Kumar, S
    Chinkara, A
    POLYMERS & POLYMER COMPOSITES, 2005, 13 (05): : 467 - 477
  • [8] Synthesis and characterization of copolymers of N-p-chlorophenylmaleimide with butyl acrylate
    Shah, BA
    Shah, AV
    Desai, PR
    Bhandari, BN
    ASIAN JOURNAL OF CHEMISTRY, 2003, 15 (02) : 573 - 582
  • [9] Block copolymers of isoprene and tertiary butyl acrylate: Synthesis, characterization and micelle formation
    Ibrahim Unal, H., 1600, Pergamon Press Ltd, Oxford, United Kingdom (30):
  • [10] GLYCIDYL METHACRYLATE TERT-BUTYL ACRYLATE COPOLYMERS - SYNTHESIS, CHARACTERIZATION, AND THERMAL STUDIES
    DHAL, PK
    BABU, GN
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (08) : 1817 - 1829
12345