Crystal structure of (+/-)-1-({[4-(allyloxy)phenyl]sulfanyl}methyl)-2-(diphenylthiophosphoryl)ferrocene

被引：0
|
作者：
Michelot, Audric [1 ,2 ]
Sarda, Stephanie [3 ]
Daran, Jean-Claude [4 ]
Deydier, Eric [1 ,2 ]
Manoury, Eric [1 ,4 ]
机构：
[1] Univ Toulouse, UPS, INPT, F-31077 Toulouse 4, France
[2] CNRS, LCC, IUT, Dept Chim, F-81104 Castres, France
[3] Univ Toulouse 3, CIRIMAT, Equipe PPB, ENSIACET Bur 2r1 5, F-31432 Toulouse, France
[4] Lab Chim Coordinat, 205 Route Narbonne, F-31077 Toulouse 04, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; ferrocenyl ligands; planar chirality; asymmetric catalysis;
D O I：
10.1107/S2056989015013560
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Fe(C5H5)(C27H24OPS2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(allyloxy)phenyl]sulfanyl} methyl and diphenylthiophosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclopentadienyl ring plane to which they are attached. In the crystal, C-H center dot center dot center dot S hydrogen bonds link the molecules into a ribbon running parallel to the ((1) over bar 10) plane. C-H center dot center dot center dot pi interactions link the ribbons to form a three-dimensional network.
引用
收藏
页码：972 / +
页数：11
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