TORSIONAL ANGLE DECOMPRESSION IS NOT THE SOURCE OF FACIAL SELECTIVITY IN DIELS-ALDER CYCLOADDITIONS INVOLVING CYCLIC DIENES FUSED TO BICYCLIC FRAMEWORKS - THE CASE-STUDY OF 1,2,3,4,6,7-HEXAHYDRO-1,4-METHANONAPHTHALENE

被引：13

作者：

HICKEY, ER ^{[1
]}

PAQUETTE, LA ^{[1
]}

机构：

[1] OHIO STATE UNIV,EVANS CHEM LABS,COLUMBUS,OH 43210

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 15期

关键词：

D O I：

10.1016/0040-4039(94)85206-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrocarbon 3 has been synthesized and shown to enter into Diels-Alder cycloaddition preferentially from the top face. This behavior, and that of 2, cannot be accounted for in terms of torsional strain minimization.

引用

页码：2309 / 2312

页数：4