ULTRAHIGH MASS RESOLUTION GLOW-DISCHARGE MASS-SPECTROMETRY - DIRECT ANALYSIS OF HEAVY ISOTOPE MIXTURES

被引：11
|
作者：
WATSON, CH
WRONKA, J
LAUKIEN, FH
BARSHICK, CM
EYLER, JR
机构：
[1] OAK RIDGE NATL LAB,OAK RIDGE,TN 37831
[2] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611
来源：
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 1993年 / 48卷 / 11期
关键词：
D O I：
10.1016/0584-8547(93)80131-D
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
A number of advantages can be realized in the coupling of glow discharge (GD) sources to Fourier transform ion cyclotron resonance (FTICR) mass spectrometers. Foremost among these is mass resolving power in the range of 1 part in 200 000-700 000, a considerable improvement over all currently available commercial instrumentation, which has a maximum resolution of 20000. At the higher resolving power, closely spaced isotopic pairs such as238U and238Pu, 198Hg and 198Pt, and 204Pb and 204Hg can be analyzed without the conventional time consuming chemical separation step that normally precedes an isotopic measurement. © 1993.
引用
收藏
页码：1445 / 1448
页数：4
相关论文
共 50 条
  • [1] DIRECT ANALYSIS OF IMPURITIES IN SOLIDS WITH GLOW-DISCHARGE MASS-SPECTROMETRY
    LEE, KB
    MOON, DW
    LEE, KW
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1989, 10 (06) : 524 - 529
  • [2] GLOW-DISCHARGE MASS-SPECTROMETRY
    HARRISON, WW
    BENTZ, BL
    [J]. PROGRESS IN ANALYTICAL SPECTROSCOPY, 1988, 11 (01): : 53 - 110
  • [3] GLOW-DISCHARGE MASS-SPECTROMETRY
    HARRISON, WW
    HESS, KR
    MARCUS, RK
    KING, FL
    [J]. ANALYTICAL CHEMISTRY, 1986, 58 (02) : A341 - &
  • [4] ANALYSIS OF SOILS BY GLOW-DISCHARGE MASS-SPECTROMETRY
    DUCKWORTH, DC
    BARSHICK, CM
    SMITH, DH
    [J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1993, 8 (06) : 875 - 879
  • [5] ANALYSIS OF SOLIDS BY GLOW-DISCHARGE MASS-SPECTROMETRY
    WEBB, PM
    SANDERSON, NE
    [J]. ELECTRONICS & WIRELESS WORLD, 1987, 93 (1620): : 997 - 999
  • [6] GLOW-DISCHARGE MASS-SPECTROMETRY FOR ELEMENTAL ANALYSIS
    COBURN, JW
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, : 68 - 68
  • [7] ISOTOPE RATIO MEASUREMENTS USING GLOW-DISCHARGE MASS-SPECTROMETRY
    RICIPUTI, LR
    DUCKWORTH, DC
    BARSHICK, CM
    SMITH, DH
    [J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1995, 146 : 55 - 64
  • [8] MEASUREMENT OF ISOTOPE RATIOS IN SOLIDS BY GLOW-DISCHARGE MASS-SPECTROMETRY
    ECKER, KH
    PRITZKOW, W
    [J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1994, 349 (1-3): : 207 - 208
  • [9] ANALYSIS OF SOLUTION RESIDUES BY GLOW-DISCHARGE MASS-SPECTROMETRY
    BARSHICK, CM
    DUCKWORTH, DC
    SMITH, DH
    [J]. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 1993, 4 (01) : 47 - 53
  • [10] APPLICATION OF GLOW-DISCHARGE MASS-SPECTROMETRY TO THE STEEL ANALYSIS
    CHIBA, K
    [J]. TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN, 1986, 72 (05): : S413 - S413
12345