KINETICS OF THE REACTION OF CHLORINE WITH FORMIC-ACID IN AQUEOUS SULFURIC-ACID

被引：16
|
作者：
HOQ, MF
INDU, B
ERNST, WR
NEUMANN, HM
机构：
[1] GEORGIA INST TECHNOL,SCH CHEM ENGN,ATLANTA,GA 30332
[2] GEORGIA INST TECHNOL,SCH CHEM & BIOCHEM,ATLANTA,GA 30332
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 02期
关键词：
D O I：
10.1021/j100155a034
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In sulfuric acid solution, the rate of reaction of chlorine with formic acid is proportional to formic acid and chlorine concentrations and is inversely proportional to the acidity function h}. The kinetic parameters are nearly identical with those for the reduction of bromine to bromide ions by formic acid. The two reactions a appear to follow similar mechanism-equilibrium ionization of formic acid followed by direct reaction of a formate ion with a hologen molecule.
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页码：681 / 683
页数：3
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