KINETICS OF THE THERMAL-DECOMPOSITION OF BIS(2,2-DINITROPROPYL)-N-FLUOROAMINE

被引：1

作者：

KORSUNSKII, BL ^{[1
]}

KOREPIN, AG ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST PHYS CHEM,CHERNOGOLOVKA 142432,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 05期

关键词：

FLUOROAMINES; THERMAL DECOMPOSITION; NITROCOMPOUNDS; KINETICS;

D O I：

10.1007/BF00696915

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the thermal decomposition of bis(2,2-dinitropropyl)-N-fluoroamine are studied in the liquid phase. The reaction is autocatalytic in a melt. In dilute solution, the reaction rate is described by the first-order law. It is tens of times faster in polar sulfolan than in weakly polar dimethyl phthalate. A mechanism of the decomposition involving the formation of a cyclic transition state at the first, limiting stage of the process is suggested.

引用

页码：847 / 850

页数：4

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