EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM IN STEELS AND PETROLEUM CRUDES WITH MANDELOHYDROXAMIC ACID (MHA)

被引:0
|
作者
MARTINEZVIDAL, JL
GONZALEZMURCIA, V
SALINAS, F
机构
[1] Univ of Coll, Spain
来源
INDIAN JOURNAL OF TECHNOLOGY | 1989年 / 27卷 / 09期
关键词
Petroleum Analysis - Vanadium Determination - Spectrophotometers - Vanadium Compounds - Spectroscopic Analysis;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A spectrophotometric method for the determination of vanadium, based on the extraction in Adogen 464-toluene solution of the mixed ligand complex with MHA, V(V) and oxalate, is proposed. The method allows determination of 21-90 μg of V(V). The values of the error and molar absorptivity are 0.9% and 15,700L mol-1 cm-1, respectively. The levels of interference caused by several foreign ions have been established. The method has been applied with success to the determination of vanadium in petroleum crudes and steels.
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页码:451 / 453
页数:3
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