AN EFFICIENT HETEROGENIZED PALLADIUM CATALYTIC-SYSTEM FOR THE REDUCTIVE CARBONYLATION OF NITROBENZENE TO METHYL-N-PHENYLCARBAMATE

被引：8

作者：

CHOUDARY, BM ^{[1
]}

RAO, KK ^{[1
]}

PIROZHKOV, SD ^{[1
]}

LAPIDUS, AL ^{[1
]}

机构：

[1] ND ZELINSKII INST ORGAN CHEM,MOSCOW,RUSSIA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 88卷 / 01期

关键词：

CARBONYLATION; METHYL-N-PHENYLCARBAMATE; MONTMORILLONITE; PALLADIUM; PYRIDINE; REDUCTION;

D O I：

10.1016/0304-5102(93)E0250-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly active and selective heterogenised homogeneous catalyst, montmorillonitebipyridinepalladium (II) acetate complex for the reductive carbonylation of nitrobenzene to methyl N-phenylcarbamate is reported. With the additional advantages such as ease of filterability and reusability for several cycles with consistent activity and selectivity, the heterogenised system will become practical alternative to the other systems described earlier.

引用

页码：23 / 30

页数：8

共 32 条

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KOLMAKOV, AO
TARASOV, EN
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ALEKSANDROV, YA
ZHURNAL OBSHCHEI KHIMII, 1988, 58 (01): : 238 - 239
[2] CATALYTIC REDUCTIVE CARBONYLATION OF NITROBENZENE TO METHYL N-PHENYLCARBAMATE
MACHO, V
MORAVEK, S
ILAVSKY, J
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[3] Palladium and silver reductive catalyzed carbonylation of nitrobenzene to methyl N-phenylcarbamate
Santi, R
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Panella, F
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[4] CARBONYLATION OF NITROBENZENE BY HYDROGEN OXIDE TO METHYL-N-PHENYLCARBAMATE IN THE PRESENCE OF THE SODIUM SULFIDE-ACTIVATOR SYSTEM
ALEKSANDROV, YA
KOLMAKOV, AO
REDOSHKIN, BA
TARASOV, EN
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VOJCEK, L
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[6] The carbonylation reaction of nitrobenzene to methyl phenylcarbamate: Highly efficient promoters for the palladium-phenanthroline catalytic system based on phosphorus acids
Ragaini, F
Cognolato, C
Gasperini, M
Cenini, S
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (25) : 2886 - 2889
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SUTULO, AG
ZHURNAL OBSHCHEI KHIMII, 1994, 64 (06): : 1011 - 1016
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Cenini, S
ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (01) : 63 - 71
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Ferretti, Francesco
Gallo, Emma
Ragaini, Fabio
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 771 : 59 - 67

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