XPS STUDIES OF SELF-ASSEMBLED MULTILAYER FILMS

被引：67
|
作者：
FREEMAN, TL
EVANS, SD
ULMAN, A
机构：
[1] UNIV LEEDS,DEPT PHYS,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND
[2] POLYTECH INST NEW YORK,DEPT CHEM,BROOKLYN,NY 11201
来源：
LANGMUIR | 1995年 / 11卷 / 11期
关键词：
D O I：
10.1021/la00011a038
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Self-assembled-mono- and multilayer films have been formed via selective ionic interactions.(1) Two types of molecule have been used, straight chain mercaptoalkanoic acids and those containing chromophores: HS(CH2)(15)COOH and HS(CH2)(11)O-C6H4-SO2(CH2)(5)COOH. To better understand the formation process, XPS studies have been performed. Models are presented for various possible orientational structures, and evidence for a preferred orientation is given. The oxidation state of the copper ions within the films has been unambiguously determined.
引用
收藏
页码：4411 / 4417
页数：7
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