THE 1ST UNSUBSTITUTED METALLABENZENE COMPLEX [RU2(ETA-5-C5ME5)2(ETA-2,ETA-5-C5H5)(SIME3)]

被引:24
|
作者
LIN, WB [1 ]
WILSON, SR [1 ]
GIROLAMI, GS [1 ]
机构
[1] UNIV ILLINOIS,SCH CHEM SCI,505 S MATHEWS AVE,URBANA,IL 61801
关键词
D O I
10.1039/c39930000284
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of the silyl/methylene complex [Ru2(eta5-C5Me5)2(mu-CH2)(SiMe3)Cl] with acetylene gives the first unsubstituted metallabenzene complex [Ru2(eta5-C5Me5)2(eta2,eta5,-C5H5)(SiMe3)], which has been characterised by NMR spectroscopy and X-ray crystallography.
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页码:284 / 285
页数:2
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