OPENING OF EPOXIDES TO OLEFINS OR HALOHYDRINS WITH VANADIUM(II)-TETRAHYDROFURAN OR VANADIUM(III)-TETRAHYDROFURAN COMPLEXES

被引：0
|
作者：
INOKUCHI, T
KAWAFUCHI, H
TORII, S
机构：
[1] TOYAMA NATL COLL TECHNOL,TOYAMA 939,JAPAN
[2] OKAYAMA UNIV,FAC ENGN,DEPT APPL CHEM,OKAYAMA 700,JAPAN
来源：
SYNLETT | 1992年 / 06期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of epoxides were deoxygenated to give the corresponding alkenes through the use of a [V2Cl3(THF)6]2[Zn2Cl6] complex prepared from VCl3(THF)3 and zinc. The reaction proceeds with a partial inversion of the configuration of the acyclic cis epoxide. Treatment of the epoxides with the vanadium(III) reagent, VCl3(THF)3, afforded the corresponding chlorohydrins in good yields.
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页码：510 / 512
页数：3
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