ASSIGNMENT OF STRUCTURES TO OLIGOSACCHARIDES PRODUCED BY ENZYMATIC DEGRADATION OF A BETA-D-GLUCAN FROM BARLEY BY H-1-NMR AND C-13-NMR SPECTROSCOPY

被引：48
|
作者：
BOCK, K [1 ]
DUUS, JO [1 ]
NORMAN, B [1 ]
PEDERSEN, S [1 ]
机构：
[1] NOVO NORDISK A-S,DK-2880 BAGSVAERD,DENMARK
来源：
CARBOHYDRATE RESEARCH | 1991年 / 211卷 / 02期
关键词：
D O I：
10.1016/0008-6215(91)80093-3
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The structures of one tri-(1), two tetra-(2 and 3), and one hexa-saccharide (4) produced by treatment of barley flour, after removal of the starch components, with a fungal beta-D-glucanase (Finizyme) have been assigned on the basis of H-1- and C-13-n.m.r. data as follows: beta-D-Glcp-(1 --> 3)-beta-D-Glcp-(1 --> 4)-D-Glcp (1), beta-D-Glcp-(1 --> 4)-beta-D-Glcp-(1 --> 3)-beta-D-Glcp-(1 --> 4)-D-Glcp (2), beta-D-Glcp-(1 --> 3)-beta-D-Glcp-(1 --> 4)-beta-D-Glcp-(1 --> 4)-D-Glcp (3), and beta-D-Xylp-(1 --> 4)-[alpha-L-Araf-(1 --> 3)]-[alpha-L-Araf-(1 --> 2)]-beta-D-Xylp-(1 --> 4)-beta-D-Xylp-(1 --> 4)-D-Xylp (4).
引用
收藏
页码：219 / 233
页数：15
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