CHEMICAL EFFECTS OF STERIC STRAINS .22. RATES OF SOLVOLYSIS OF DIMETHYL(2-NORBORNYL)CARBINYL PARA-NITROBENZOATES AND OF QUATERNIZATION OF 2-DIMETHYLAMINONORBORNANES - CRITICAL-EXAMINATION OF SIGNIFICANCE OF STERIC FACTORS IN CHEMISTRY OF EXO-NORBORNYL DERIVATIVES AND ENDO-NORBORNYL DERIVATIVES

被引：16

|

作者：

BROWN, HC

RAVINDRANATHAN, M

机构：

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1978年 / 100卷 / 06期

关键词：

D O I：

10.1021/ja00474a034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

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页码：1865 / 1869

页数：5

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[1] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .27. SOLVOLYSIS OF EXO-1,2-DIPHENYL-2-NORBORNYL AND ENDO-1,2-DIPHENYL-2-NORBORNYL AND ENDO-1,2-DIMETHYL-2-NORBORNYL PARA-NITROBENZOATES AND CHLORIDES - DEFINITIVE EVIDENCE FOR CLASSICAL NATURE OF 1,2-DISUBSTITUTED TERTIARY 2-NORBORNYL CATIONS AND IMPLICATIONS FOR STRUCTURE OF PARENT 2-NORBORNYL CATIONA
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[2] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .21. SOLVOLYSIS OF 2-ARYL-2-NORBORNYL AND 2-ARYL-2-CAMPHENILYL PARA-NITROBENZOATES - CRITICAL-EXAMINATION OF IMPORTANCE OF SIGMA-PARTICIPATION IN SOLVOLYSIS TERTIARY 2-NORBORNYL DERIVATIVES BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (08) : 2684 - 2690
[3] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .49. STERIC EFFECTS AS A MAJOR FACTOR IN THE EXO-ENDO RATE RATIOS FOR THE SOLVOLYSIS OF 2,7,7-TRIMETHYL-2-NORBORNYL AND 2,6,6-TRIMETHYL-2-NORBORNYL PARA-NITROBENZOATES
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[4] AN UNUSUALLY LOW EXO-ENDO RATE RATIO IN SOLVOLYSIS OF 2,7,7-TRIMETHYL-2-NORBORNYL P-NITROBENZOATES . EVIDENCE FOR STERIC EFFECTS AS A MAJOR FACTOR IN EXO-ENDO RATE AND PRODUCT RATIOS OF NORBORNYL DERIVATIVES
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[5] AN UNUSUALLY HIGH EXO-ENDO RATE RATIO IN SOLVOLYSIS OF 2,6,6-TRIMETHYL-2-NORBORNYL P-NITROBENZOATES . FURTHER EVIDENCE FOR STERIC EFFECTS AS A MAJOR FACTOR IN EXO-ENDO RATE RATIOS OF NORBORNYL DERIVATIVES
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[6] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .30. SOLVOLYSIS OF 2-(5'-COUMARANYL)-2-NORBORNYL PARA-NITROBENZOATES - EVIDENCE FOR THE UNIMPORTANCE OF SIGMA-PARTICIPATION AS A FACTOR IN THE HIGH EXO-ENDO RATE AND PRODUCT RATIOS REALIZED IN THE SOLVOLYSIS OF EXCEPTIONALLY HIGHLY STABILIZED TERTIARY 2-NORBORNYL DERIVATIVES
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1978, 44 (01): : 133 - 136
[7] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .20. SOLVOLYSIS OF 2-PARA-ANISYL-2-NORBORNYL AND 2-PARA-ANISYL-2-CAMPHENILYL PARA-NITROBENZOATES - EVIDENCE FOR UNIMPORTANCE OF SIGMA-PARTICIPATION AS A FACTOR IN HIGH EXO-ENDO RATE AND PRODUCT RATIOS REALIZED IN SOLVOLYSIS OF HIGHLY STABILIZED TERTIARY 2-NORBORNYL DERIVATIVES
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (08) : 2679 - 2683
[8] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .32. EFFECT OF INCREASING ELECTRON DEMAND ON THE RATES OF SOLVOLYSIS OF 2-ARYL-3-METHYLENE-2-NORBORNYL PARA-NITROBENZOATES - HIGH EXO-ENDO RATE AND PRODUCT RATIOS FOR TERTIARY DERIVATIVES OF THE ACCEPTED CLASSICAL 3-METHYLENE-2-NORBORNYL SYSTEM
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (20): : 3536 - 3540